Direct synthesis of phenol by novel [FeFe]-hydrogenase model complexes as catalysts of benzene hydroxylation with H2O2

Synthesis and characterization of copper(ii) complexes with multidentate ligands as catalysts for the direct hydroxylation of benzene to phenol.

Four copper(ii) complexes with multidentate ligands, ([CuL1Cl2]), ([Cu(HL2)Cl2]), ([Cu2(L2)2](ClO4)2) and ([CuL3(HOCH3)ClO4]) {L1 = N,N-bis((pyridin-2-yl)methyl) prop-2-yn-1-amine, HL2 = 2-((((1-methyl-1H-imidazol-2-yl)methyl)(pyridin-2-ylmethyl)amino)methyl)phenol and HL3 = 2-((((1-methyl-1H-imidazol-2-yl)methyl)(pyridin-2-ylmethyl)amino)methyl)-2-t-butyl-phenol} are reported. The complexes we...

Synthetic [FeFe] Hydrogenase Active Site Model Complexes

XAFS Study on Re/Zeolite Catalysts for Direct Phenol Synthesis from Benzene with Molecular Oxygen

Introduction Phenol is an important chemical in industry but has been produced from benzene by the three-steps of cumene process. Direct phenol synthesis from benzene is one of the important subjects. However, no selective catalyst with good performance in an economically and environmentally favourable benzene-O2 system has been discovered to date. We have found Re/HZSM-5 promoted the direct ph...

Direct oxidation of benzene to phenol in liquid phase by H2O2 over vanadium catalyst supported on highly ordered nanoporous silica

Vanadium supported on highly ordered nanoporous silica (VOx-LUS-1) was synthesized and characterized by XRD, Nitrogen adsorption‑desorption isotherms and UV-visible spectrophotometer. Direct oxidation of benzene to phenol in liquid phase by H2O2 peroxide were examined by using various solvents (methanol, acetone, acetic acid, acetonitryl). The maximum yield (25%) and selectivity (73%) of the ph...

single-step synthesis of multi-component spirobarbiturates using ionic liquids and synthesis of substituted pyridine filled with catalysts supported on solid substrate

in this thesis, a better reaction conditions for the synthesis of spirobarbiturates catalyzed by task-specific ionic liquid (2-hydroxy-n-(2-hydroxyethyl)-n,n-dimethylethanaminium formate), calcium hypochlorite ca(ocl)2 or n-bromosuccinimide (nbs) in the presence of water at room temperature by ultrasonic technique is provided. the design and synthesis of spirocycles is a challenging task becaus...